High-performance Deep Blue “Hot Exciton” Materials Based on Anthracene

نویسندگان

چکیده

è“å ‰OLEDææ–™æ˜¯ç”µè‡´å‘å ‰é¢†åŸŸçš„å ³é”®å’Œéš¾ç‚¹ã€‚åŸºäºŽé«˜èƒ½æ¿€å‘æ€è½¬æ¢çš„â€œçƒ­æ¿€å­â€ææ–™è¡¨çŽ°å‡ºä¼˜å¼‚è“å ‰ææ–™çš„æ½œèƒ½ã€‚æœ¬æ–‡é€šè¿‡è°ƒèŠ‚ç»™å—ä½“çš„æŽ¨æ‹‰ç”µå­èƒ½åŠ›ï¼Œä»¥è’½ä¸ºæ ¸å¿ƒæž„ç­‘å•å ƒã€ä¸‰è‹¯åŸºè‹¯ä¸ºå¼±ç»™ä½“ã€è‹¯æ°°åŸºä¸ºå—ä½“ï¼Œè®¾è®¡åˆæˆäº†ä¸€ç§æ–°åž‹D⁃π⁃A结构分子TACNã€‚æ‰­æ›²çš„ä¸‰è‹¯åŸºè‹¯æä¾›äº†é«˜åº¦æ‰­æ›²çš„åˆ†å­æž„è±¡ï¼Œæœ‰æ•ˆå‡å¼±äº†èšé›†æ€ä¸‹çš„çŒç­æ•ˆåº”ï¼Œå› æ­¤TACNè¡¨çŽ°å‡ºé«˜çš„è§å ‰é‡å­äº§çŽ‡ï¼ˆèšé›†æ€ä¸‹47%)。实验结果和理论分析表明,TACNå ·å¤‡â€œçƒ­æ¿€å­â€ç‰¹å¾ï¼Œå ¶å¤§çš„T2⁃T1能隙(1.45 eV)有效阻碍了从T2到T1çš„å† è½¬æ¢ï¼ˆIC)过程,而小的T2⁃S1能差(0.18 eV,T2> S1)有利于促进反向系间窜越(RISC)过程。基于TACN的非掺杂器件表现出深蓝色发射(λmax= 444 nm),半峰宽(FWHM)为59 nmï¼Œè‰²åæ ‡ä¸ºï¼ˆ0.17,0.13ï¼‰ã€‚å ¶æœ€å¤§å¤–é‡å­æ•ˆçŽ‡ï¼ˆEQEmax)为8.3%,相应的激子利用率(EUE)最高为88.7%。

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ژورنال

عنوان ژورنال: Chinese Journal of Luminescence

سال: 2023

ISSN: ['1000-7032']

DOI: https://doi.org/10.37188/cjl.20230137